Publications 2005

  • Proton Affinities and relative Basicities of two 1,4,7-triazacyclononanes, Me3TACN and TP-TACN. Quantum-chemical ab initio calculations, solution measurements, and the structure of [TP-TACN•H]2+ in the solid state
    N. Meyer, C. Bolm, G. Raabe, U. Kölle, Tetrahedron 2005, 61, 12371–12376.
     
  • Asymmetric alcoholysis of meso-anhydrides mediated by alkaloids
    C. Bolm, I. Atodiresei, I. Schiffers, Org. Synth. 2005, 82, 120–125.
     
  • Planar-Chiral Cyrhetrenes for the Rhodium-Catalyzed Asymmetric 1,4-Addition and the Hydrogenation of Enamides
    R. T. Stemmler, C. Bolm, J. Org. Chem. 2005, 70, 9925–9931.
     
  • Silver-catalyzed imination of sulfoxides and sulfides
    G. Y. Cho, C. Bolm, Org. Lett. 2005, 7, 4983–4985.
     
  • ZnMe2 mediated addition of phenylacetylene to aldehydes and ketones
    P. G. Cozzi, J. Rudolph, C. Bolm, P.-O. Norrby, C. Tomasini, J. Org. Chem. 2005, 70, 5733–5736.
     
  • Boronic acids as versatile aryl sources for the highly enantioselective synthesis of chiral diarylmethanols on multi-gram scale (PSP)
    J. Rudolph, F. Schmidt, C. Bolm, Synthesis 2005, 840–842.
     
  • Diphenylphosphinosulfoximines as Ligands in Iridium-catalyzed Asymmetric Imine Hydrogenations
    C. Mössner, C. Bolm, Angew. Chem. 2005, 117, 7736–7739; Angew. Chem. Int. Ed. 2005, 44, 7564–7567.
     
  • Highly Modular Synthesis of C1-Symmetric Aminosulfoximines and their Use as Ligands in Copper-Catalyzed Asymmetric Mukaiyama-Aldol Reactions
    M. Langner, P. Rémy, C. Bolm, Chem. Eur. J. 2005, 11, 6254–6265.
     
  • Novel Rhodium Complexes with Ferrocene-Based N-Heterocylic Carbenes: Synthesis, Structure and Catalysis
    Y. Yuan, G. Raabe, C. Bolm, J. Organomet. Chem. 2005, 690, 5747–5752.
     
  • Iron(III)-Catalyzed Tandem Sequential Methanol Oxidation/Aldol Coupling
    V. Lecomte, C. Bolm, Adv. Synth. Catal. 2005, 347, 1666–1672.
     
  • Cu(OAc)2-catalyzed N-Arylations of Sulfoximines with Aryl Boronic Acids
    C. Mössner, C. Bolm, Org. Lett. 2005, 7, 2667–2669.
     
  • Ethylene-Bridged Bissulfoximines in Copper-Catalyzed Enantioselective Hetero-Diels-Alder Reactions
    C. Bolm, M. Verrucci, O. Simic, C. P. R. Hackenberger, Adv. Synth. Catal. 2005, 347, 1696–1700.
     
  • Metal-free imination of sulfoxides and sulfides
    G. Y. Cho, C. Bolm, Tetrahedron Lett. 2005, 46, 8007–8008.
     
  • Efficient Copper-Catalyzed N-Arylation of Sulfoximines with Aryl Iodides and Aryl Bromides
    J. Sedelmeier, C. Bolm, J. Org. Chem. 2005, 70, 6904–6906.
     
  • BINOL-derived N-phosphino sulfoximines as ligands for asymmetric catalysis
    M. T. Reetz, O. G. Bondarev, H.-J. Gais, C. Bolm, Tetrahedron Lett. 2005, 46, 5643–5646.
     
  • Ionic liquids as additives in the pig liver esterase (PLE) catalysed synthesis of chiral disubstituted malonates
    S. Wallert, K. Drauz, I. Grayson, H. Gröger, P. Dominguez de Maria, C. Bolm, Green Chem. 2005, 7, 601–605.
     
  • Enzymatische Reaktionen in Gegenwart ionischer Additive
    S. Wallert, J. I. Grayson, K. Drauz, H. Gröger, C. Bolm, P. Dominguez de Maria, F. Chamouleau, Deutsche Patentanmeldung DE 10 2004 034 216.4 (14.7.2004);
    Internationale Patentanmeldung (PTC) von DE 10 2004 034 216.4 (14.7.2004); Juni 2005.
     
  • A high-throughput screening approach for the determination of additive effects in organozinc addition reactions to aldehydes
    J. Rudolph, M. Lormann, C. Bolm, S. Dahmen, Adv. Synth. Catal. 2005, 347, 1361–1368.
     
  • Synthesis of New Chiral Hydroxy Oxazolines and their Use in the Catalyzed Asymmetric Phenyl Transfer to Aldehydes
    C. Bolm, F. Schmidt, L. Zani, Tetrahedron: Asymmetry 2005, 16, 1367–1376.
     
  • Ring Closing Metathesis (RCM) for the Synthesis of Cyclic Sulfoximines
    C. Bolm, H. Villar, Synthesis 2005,1421–1424.
     
  • Synthesis of novel silylated 1,2,4-triazin-5-ones
    C. Bolm, A. Kasyan, S. Saladin, Tetrahedron Lett. 2005, 46, 4049–4051.
     
  • Enantiopure α-Silyl-Substituted α-Hydroxyacetic Acids using O–H Insertion Methodology and Boron-Based Asymmetric Reductions
    C. Bolm, S. Saladin, A. Claßen, A. Kasyan, E. Veri, G. Raabe, Synlett 2005, 461–464.
     
  • Copper- and Palladium-Catalyzed Allylic Acyloxydations
    J.-C. Frison, J. Legros, C. Bolm, in Handbook of CH Transformations (Ed.: G. Dyker), Wiley/VCH, Weinheim, 2005, 445–454.
     
  • Organosilanols as Catalysts in Asymmetric Aryl Transfer Reactions
    S. Özçubukçu, F. Schmidt, C. Bolm, Org. Lett. 2005, 7, 1407–1410.
     
  • Palladium-catalyzed α-arylation of sulfoximines
    G. Y. Cho, C. Bolm, Org. Lett. 2005, 7, 1351–1354.
     
  • Protonated Chrial Catalysts: New and Versatile Tools for Asymmetric Synthesis
    C. Bolm, I. Schiffers, L. Zani, T. Rantanen, Angew. Chem. 2005, 117, 1788–1793; Angew. Chem.Int. Ed. 2005, 44, 1758–1763.
     
  • C1-Symmetric Aminosulfoximines as Ligands in Copper-Catalyzed Carbonyl-Ene Reactions
    M. Langner, P. Rémy, C. Bolm, Synlett 2005, 781–784.
     
  • Highly symmetrical amino acid-derived N,N'-diacylated sulfodiimines
    J. R. Dehli, C. Bolm, Synthesis 2005, 1058–1060.
     
  • Synthesis and Palladium Catalyzed Coupling Reactions of Enantiopure p-Bromo-phenylmethyl Sulfoximine
    G. Y. Cho, H. Okamura, C. Bolm, J. Org. Chem. 2005, 70, 2346–2349.
    Corrigendum: J. Org. Chem. 2010, 75, 522.
     
  • Synthesis of enamines, enol ethers and related compounds by cross-coupling reactions
    J. R. Dehli, J. Legros, C. Bolm, Chem. Commun. 2005, 973–986.
     
  • New insights into the stereoselectivity of the aryl zinc addition to aldehydes
    J. Rudolph, C. Bolm, P.-O. Norrby, J. Am. Chem. Soc. 2005, 117, 1548–1552.
     
  • Investigations on the Iron-Catalyzed Asymmetric Sulfide Oxidation
    J. Legros, C. Bolm, Chem. Eur. J. 2005, 11, 1086–1092.
     
  • Asymmetric Diethyl- and Diphenylzinc Additions to Aldehydes Using a Fluorine Containing Chiral Amino Alcohol: A Striking Temperature Effect on the Enantioselectivity, a Minimal Amino Alcohol Loading, and an Efficient Recycling of the Amino Alcohol
    J. K. Park, H. G. Lee, C. Bolm, B. M. Kim, Chem. Eur. J. 2005, 11, 945–950.
     
  • Boronic acids as versatile aryl sources for the highly enantioselective synthesis of chiral diarylmethanols on multi-gram scale
    J. Rudolph, F. Schmidt, C. Bolm, Synthesis 2005, 840–842.
     
  • Planar-Chiral Imidazolium Salts in the Asymmetric Rhodium-catalyzed 1,2-Addition of Aryl Boronic Acids to Aldehydes
    T. Focken, J. Rudolph, C. Bolm, Synthesis 2005, 429–436.
     
  • Iron-catalysed C–H oxidation of hydrocarbons with hydrogen peroxide under mild conditions
    C. Pavan, J. Legros, C. Bolm, Adv. Synth. Catal. 2005, 347, 703–705.
     
  • A General Copper-Promoted Coupling of Sulfoximines with Vinyl Bromides
    J. R. Dehli, C. Bolm, Adv. Synth. Catal. 2005, 347, 239–242.
     
  • Applications of Catalytic Asymmetric Sulfide Oxidations to the Synthesis of Biologically Active Sulfoxides
    J. Legros, J. R. Dehli, C. Bolm, Adv. Synth. Catal. 2005, 347, 19–31.