Publications 2018

Mechanistic studies of base-catalysed lignin depolymerisation in dimethyl carbonate
S. Dabral, J. Engel, J. Mottweiler, S. S. M. Spoehrle, C. W. Lahive, C. Bolm, Green Chem. 2018, 20, 170–182.

Iron(II)-Catalyzed Direct Synthesis of NH Sulfoximines from Sulfoxides
H. Yu, Z. Li, C. Bolm, Angew. Chem. 2018, 130, 330–333; Angew. Chem. Int. Ed. 2018, 57, 324–327.

Tetrahydrobenzo[c]thieno[2,1-e]isothiazole 4-Oxides: Three-Dimensional Heterocycles as Cross-Coupling Building Blocks
P. Lamers, C. Bolm, Org. Lett. 2018, 20, 116–118.

Mechanochemical Activation of Iron Cyano Complexes: A Prebiotic Impact Scenario for the Synthesis of α-Amino Acid Derivatives
C. Bolm, R. Mocci, C. Schumacher, M. Turberg, F. Puccetti, J. G. Hernández, Angew. Chem. 2018, 130, 2447–2450; Angew. Chem. Int. Ed. 2018, 57, 2423–2426.
Selected as Very Important Paper. Highlighted in Chemistry World. Selected by Y. Uozumi and G. Hamasaka for Synfacts 2018, 14, 537.

New ATR inhibitors for the use in cancer therapy
C. Bolm, C. M. Hendriks, B. Lüscher, J. Hartkamp; WO application 2018029117, February 15, 2018.

Mechanochemical Oxidation and Cleavage of Lignin β-O-4 Model Compounds and Lignin
S. Dabral, H. Wotruba, J. G. Hernández, C. Bolm, ACS Sustainable Chem. Eng. 2018, 6, 3242–3254.

Sulfoximidations of Benzylic C–H Bonds by Photocatalysis
H. Wang, D. Zhang, C. Bolm, Angew. Chem. 2018, 130, 5965–5968; Angew. Chem. Int. Ed. 2018, 57, 5863–5866.

N-Arylated Sulfoximines as Cross-Coupling Building Blocks
A.-K. Bachon, A.-D. Steinkamp, C. Bolm, Adv. Synth. Catal. 2018, 360, 1088–1093.

Papain-catalysed mechanochemical synthesis of oligopeptides by milling and twin-screw extrusion: application in the Juliá–Colonna enantioselective epoxidation
K. J. Ardila-Fierro, D. E. Crawford, A. Körner, S. L. James, C. Bolm, J. G. Hernández, Green Chem. 2018, 20, 1262–1269.

Sulforaphane Modifies Histone H3, Unpacks Chromatin, and Primes Defense
B. Schillheim, I. Jansen, S. Baum, A. Beesley, C. Bolm, U. Conrath, Plant Physiol. 2018, 176, 2395–2405.

Mechanochemical dehydrocoupling of dimethylamine borane and hydrogenation reactions using Wilkinson's catalyst
C. Schumacher, D. E. Crawford, B. Raguž, R. Glaum, S. L. James, C. Bolm, J. G. Hernández, Chem. Commun. 2018, 54, 8355–8358.

Mechanochemical Cobalt‐Catalyzed C–H Bond Functionalizations by Ball Milling
H. Cheng, J. G. Hernández, C. Bolm, Adv. Synth. Catal. 2018, 360, 1800–1804.

Nondirected Copper-Catalyzed Sulfoxidations of Benzylic C–H Bonds
H. Yu, Z. Li, C. Bolm, Org. Lett. 2018, 20, 2076–2079.

From Synthesis of Amino Acids and Peptides to Enzymatic Catalysis: A Bottom-Up Approach in Mechanochemistry
C. Bolm, J. G. Hernández, ChemSusChem 2018, 11, 1410–1420.

Synthesis of 3-Iodobenzofurans by Electrophilic Cyclization under Solventless Conditions in a Ball Mill
A. C. Mantovani, J. G. Hernández, C. Bolm, Eur. J. Org. Chem. 2018, 2458–2461.
Cover Feature: A. C. Mantovani, J. G. Hernández, C. Bolm, Eur. J. Org. Chem. 2018, 2296.

Photocatalytic difunctionalisations of alkenes with N-SCN sulfoximines
D. Zhang, H. Wang, C. Bolm, Chem. Commun. 2018, 54, 5772–5775.

Cobalt-Catalyzed Oxidation of the β-O-4 Bond in Lignin and Lignin Model Compounds
T. Rinesch, C. Bolm, ACS Omega 2018, 3, 8386–8392.

Altering Copper‐Catalyzed A³‐Couplings by Mechanochemistry: One‐Pot Synthesis of 1,4‐Diamino‐2‐butynes from Aldehydes, Amines, and Calcium Carbide
M. Turberg, K. J. Ardila-Fierro, C. Bolm, J. G. Hernández, Angew. Chem. 2018, 130, 10878–10882; Angew. Chem. Int. Ed. 2018, 57, 10718–10722.

Mechanochemical Rhodium(III)‐ and Gold(I)‐Catalyzed C–H Bond Alkynylations of Indoles under Solventless Conditions in Mixer Mills
G. N. Hermann, M. T. Unruh, S.-H. Jung, M. Krings, C. Bolm, Angew. Chem. 2018, 130, 10883–10887; Angew. Chem. Int. Ed. 2018, 57, 10723–10727.

Three‐Dimensional Heterocycles by Iron‐Catalyzed Ring‐Closing Sulfoxide Imidation
H. Yu, Z. Li, C. Bolm, Angew. Chem. 2018, 130, 12229–12232; Angew. Chem. Int. Ed. 2018, 57, 12053–12056.

Die (langen) Wege vom Grundlagenexperiment bis zum Prozess oder Material [including English article version]
C. Bolm, W. Leitner, M. Schmitz, Forschungsmagazin RWTH THEMEN – Profilbereich „Molecular Science & Engineering“ (MSE), Summer term 2018, 4–7.

Eine Lösung ohne Lösung
C. Bolm, J. G. Hernández, Forschungsmagazin RWTH THEMEN – Profilbereich „Molecular Science & Engineering“ (MSE), Summer term 2018, 12–15.

Von Enzymen, Moleküldesign und Inhibitorsynthese
C. Bolm, B. Lüscher, G. Rossetti, P. Verheugd, Forschungsmagazin RWTH THEMEN – Profilbereich „Molecular Science & Engineering“ (MSE), Summer term 2018, 76–79.

Translationale Tumor-Medizin
S. Koschmieder, C. Bolm, T. H. Brümmendorf, Forschungsmagazin RWTH THEMEN – Profilbereich „Molecular Science & Engineering“ (MSE), Summer term 2018, 80–85.

From beech wood to itaconic acid: case study on biorefinery process integration
L. Regestein, T. Klement, P. Grande, D. Kreyenschulte, B. Heyman, T. Maßmann, A. Eggert, R. Sengpiel, Y. Wang, N. Wierckx, L. M. Blank, A. Spiess, W. Leitner, C. Bolm, M. Wessling, A. Jupke, M. Rosenbaum, J. Büchs, Biotechnol. Biofuels 2018, 11, 279.

Photocatalytic Additions of 1-Sulfoximidoyl-1,2-Benziodoxoles to Styrenes
H. Wang, D. Zhang, C. Bolm, Chem. Eur. J. 2018, 24, 14942–14945.

Copper‐Catalyzed Transsulfinamidation of Sulfinamides as a Key Step in the Preparation of Sulfonamides and Sulfonimidamides
H. Yu, Z. Li, C. Bolm, Angew. Chem. 2018, 130, 15828–15831; Angew. Chem. Int. Ed. 2018, 57, 15602–15605.

Transition-Metal-Free Arylations of In-Situ Generated Sulfenates with Diaryliodonium Salts
H. Yu, Z. Li, C. Bolm, Org. Lett. 2018, 20, 7104–7106.

Organocatalytic Asymmetric Allylic Alkylations of Sulfoximines
Z. Li, M. Frings, H. Yu, G. Raabe, C. Bolm, Org. Lett. 2018, 20, 7367–7370.