Publications 2023

  • Electro-mechanochemical approach towards chloro sulfoximidations of allenes under solvent-free conditions in a ball mill
    M. M. Amer, R. Hommelsheim, C. Schumacher, D. Kong, C. Bolm, Faraday Discuss. 2023, 241, 79–90.
  • Advances in synthesis: general discussion
    A. Angerhofer, M. Baláž, V. Balema, A. M. Belenguer, R. G. Blair, E. Boldyreva, C. Bolm, L. Borchardt, A. B. Braunschweig, D. L. Browne, S. Craig, L. El Wenni, F. Emmerling, M. Ferguson, C. Fiore, T. Friščić, K. Fukushima, F. García, L. Gonnet, S. Grätz, R. A. Hernandez R., H. Ito, S. L. James, D. Karabiyikli, J. G. Kim, K. Kubota, F. Lamaty, G. I. Lampronti, J. Leitch, S. Lukin, J. Mack, L. Maini, S. Mohamed, A. Moores, K. Nagapudi, F. Puccetti, M. Tian, Q. Yu, Faraday Discuss. 2023, 241, 150–177.
  • Kinetics and basic understanding: general discussion
    A. Angerhofer, T. Auvray, V. Balema, M. Baláž, J. D. Batteas, R. G. Blair, E. Boldyreva, C. Bolm, L. Borchardt, T. H. Borchers, A. B. Braunschweig, D. L. Browne, R. W. Carpick, M. Ciaccia, S. Craig, F. Emmerling, M. Ferguson, C. Fiore, T. Friščić, S. Grätz, I. Halasz, E. Hamzehpoor, H. Ito, S. James, J. G. Kim, F. Lamaty, G. I. Lampronti, D. Laurencin, J. Leitch, E. Lu, S. Lukin, J. Mack, L. Maini, A. Martini, P. P. Mazzeo, A. A. L. Michalchuk, S. Mittelette, S. Mohamed, A. Moores, A. d. J. Mortera-Carbonell, K. Nagapudi, A. Niidu, F. Puccetti, M. Stahorský, L. Vugrin, Faraday Discuss. 2023, 241, 306–340.
  • Scale up and industrial implementation: general discussion
    M. Baláž, V. Balema, J. D. Batteas, R. G. Blair, C. Bolm, L. Borchardt, A. B. Braunschweig, S. L. Craig, F. Emmerling, M. Ferguson, T. Friščić, S. James, J. Leitch, J. Mack, S. Mohamed, K. Nagapudi, F. Puccetti, M. E. Rivas, Faraday Discuss. 2023, 241, 387–393.
  • Shear processes and polymer mechanochemistry: general discussion
    M. Baláž, V. Balema, R. G. Blair, E. Boldyreva, C. Bolm, A. B. Braunschweig, R. W. Carpick, S. L. Craig, F. Emmerling, J. P. Ewen, C. Fiore, T. Friščić, S. Grätz, I. Halasz, E. Hamzehpoor, H. Ito, J. G. Kim, G. I. Lampronti, D. Laurencin, J. Mack, L. Maini, P. P. Mazzeo, S. Mohamed, K. Nagapudi, A. Niidu, J. Vainauskas, C. Zuffa, Faraday Discuss. 2023, 241, 466–484.
  • Reshuffle Bonds by Ball Milling: A Mechanochemical Protocol for Charge-Accelerated Aza-Claisen Rearrangements
    C. Schumacher, L. Fritz, L. M. Hanek, V. Sidorin, D. Brüx, C. Bolm, Molecules 2023, 28, 807.
  • Beta-Thalassemia Minor and SARS-CoV-2: Physiopathology, Prevalence, Severity, Morbidity, and Mortality
    E. Lansiaux, E. Drouin, C. Bolm, Thalass. Rep. 2023, 13, 21–32.
    Also published as a preprint at medRxiv.
  • Matching Carbenes and Sulfoximines via Ketenes Generated from α-Diazoketones by Blue Light
    S. Pan, M. T. Passia, X. Wang, P. Wu, D. Ma, C. Bolm, Adv. Synth. Catal. 2023, 365, 31–36.
  • Effective Production of Selected Dioxolanes by Sequential Bio- and Chemocatalysis Enabled by Adapted Solvent Switching
    J.-D. Spöring, J. Wiesenthal, V. S. Pfennig, J. Gätgens, K. Beydoun, C. Bolm, J. Klankermayer, D. Rother, ChemSusChem 2023, 16, e202201981.
  • Revisiting the bromination of 3β-hydroxycholest-5-ene with CBr4/PPh3 and the subsequent azidolysis of the resulting bromide, disparity in stereochemical behavior
    C. Schumacher, J. S. Ward, K. Rissanen, C. Bolm, M. R. E. S. Aly, Beilstein J. Org. Chem. 2023, 19, 91–99.
    Also published as a preprint at Beilstein Arch.
  • Synthesis of o-Sulfinylanilines from N-Alkyl Sulfoximines and Arynes
    X. Wang, M. Frings, K. Rissanen, C. Bolm, J. Org. Chem. 2023, 88, 2666–2669.
  • Correction: PARP targeted Auger emitter therapy with [125I]PARPi-01 for triple-negative breast cancer
    R. Ambur Sankaranarayanan, A. Florea, S. Allekotte, A. T. J. Vogg, J. Maurer, L. Schäfer, C. Bolm, S. Terhorst, A. Classen, M. Bauwens, A. Morgenroth, F. M. Mottaghy, EJNMMI Res. 2023, 13, 12.
  • Correction: Auger Emitter Conjugated PARP Inhibitor for Therapy in Triple Negative Breast Cancers: A Comparative In-Vitro Study
    R. Ambur Sankaranarayanan, J. Peil, A. T. J. Vogg, C. Bolm, S. Terhorst, A. Classen, M. Bauwens, J. Maurer, F. Mottaghy, A. Morgenroth, Cancers 2023, 15, 2641.
  • Disentangling the Effect of Pressure and Mixing on a Mechanochemical Bromination Reaction by Solid-state NMR Spectroscopy
    E. Bartalucci, C. Schumacher, L. Hendrickx, F. Puccetti, I. d'Anciães Almeida Silva, R. Dervişoğlu, R. Puttreddy, C. Bolm, T. Wiegand, Chem. Eur. J. 2023, 29, e202203466.
    Also published as a preprint at ChemRxiv.
  • A Copper-Catalyzed Interrupted Domino Reaction for the Synthesis of Fused Triazolyl Benzothiadiazine-1-oxides
    R. Hommelsheim, S. Bausch, A. Selvakumar, M. M. Amer, K.-N. Truong, K. Rissanen, C. Bolm, Chem. Eur. J. 2023, 29, e202203729.
  • A One-Pot Domino Reaction Providing Fluorinated 5,6-Dihydro-1,2-thiazine 1-Oxides from Sulfoximines and 1-Trifluoromethylstyrenes
    X. Wang, K. Rissanen, C. Bolm, Org. Lett. 2023, 25, 1569–1572.
  • Cyclic Sulfoximine and Sulfonimidamide Derivatives by Copper-Catalyzed Cross-Coupling Reactions with Elemental Sulfur
    P. Wu, J. Ward, K. Rissanen, C. Bolm, Adv. Synth. Catal. 2023, 365, 522–526.
    Corrigendum: Adv. Synth. Catal. 2023, 365, 1287.
  • Synthesis of 3-amino-substituted benzothiadiazine oxides by a palladium-catalysed cascade reaction
    R. Hommelsheim, S. Bausch, R. van Nahl, J. S Ward, K. Rissanen, C. Bolm, Green Chem. 2023, 25, 3021–3026.
  • Synthesis of Sulfonyl, Sulfonimidoyl, and Sulfoxyl Fluorides under Solvent-Free Mechanochemical Conditions in a Mixer Mill by Imidazole-to-Fluorine Exchange
    M. T. Passia, M. M. Amer, J. Demaerel, C. Bolm, ACS Sustainable Chem. Eng. 2023, 11, 6838–6843.
    Experimental details are described in this video.
  • NMR in operando monitoring of mechanochemically accelerated sublimations
    F. Puccetti, T. Rinesch, S. Suljić, K. Rahimi, A. Herrmann, C. Bolm, Chem 2023, 9, 1318–1332.
    Also published as a preprint at ChemRxiv.
  • Copper-Catalyzed N-Alkylations of NH-Sulfoximines Under Visible Light
    P. Shi, Y. Tu, D. Ma, C. Bolm, Adv. Synth. Catal. 2023, 365, 1613–1617.
  • Mechanochemical Oxidative Degradation of Thienopyridine Containing Drugs: Toward a Simple Tool for the Prediction of Drug Stability
    E. F. Krake, L. Backer, B. Andres, W. Baumann, N. Handler, H. Buschmann, U. Holzgrabe, C. Bolm, T. Beweries, ACS Cent. Sci. 2023, 9, 1150–1159.
  • Synthesis of N-Monosubstituted Sulfondiimines by Metal-free Iminations of Sulfiliminium Salts
    M. T. Passia, N. Bormann, J. S. Ward, K. Rissanen, C. Bolm, Angew. Chem. Int. Ed. 2023, 62, e202305703.
    Selected as Very Important Paper.
  • The effect of methyl group rotation on 1H-1H solid-state NMR spin-diffusion spectra
    E. Bartalucci, D. J. Luder, N. Terefenko, A. A. Malär, C. Bolm, M. Ernst, T. Wiegand, Phys. Chem. Chem. Phys. 2023, 25, 19501–19511.
    Also published as a preprint at ChemRxiv.
  • Mechanochemical difluoromethylations of alcohols
    P. van Bonn, J. Ke, C. Weike, J. S. Ward, K. Rissanen, C. Bolm, CCS Chem. 2023, 5, 1737–1744.
  • Mechanochemical Synthesis of Stimuli Responsive Microgels
    C. Hu, P. van Bonn, D. E. Demco, C. Bolm, A. Pich, Angew. Chem. Int. Ed. 2023, 62, e202305783.
  • Opportunities and Challenges in Applying Solid-State NMR Spectroscopy in Organic Mechanochemistry
    I. d'Anciães Almeida Silva, E. Bartalucci, C. Bolm, T. Wiegand, Adv. Mater. 2023, 35, 2304092.
    Also published as a preprint at ChemRxiv.
  • Corrigendum: Acylsilanes in Iridium-Catalyzed Directed Amidation Reactions and Formation of Heterocycles via Siloxycarbenes
    P. Becker, R. Pirwerdjan, C. Bolm, Angew. Chem. Int. Ed. 2023, 62, e202314567.