Publications 2000

  • A novel enantiopure proline-derived triazacyclononane: synthesis, structure and application of its manganese complex
    C. Bolm, N. Meyer, G. Raabe, T. Weyhermüller, E. Bothe, Chem. Commun. 2000, 2435–2436.

     
  • Practical and Highly Enantioselective Ring Opening of Cyclic Meso-Anhydrides Mediated by Cinchona Alkaloids
    C. Bolm, I. Schiffers, C. L. Dinter, A. Gerlach, J. Org. Chem. 2000, 65, 6984–6991.

     
  • Asymmetric, Dihydroxylations and Aminohydroxylations
    C. Bolm, J. P. Hildebrand, K. Muñiz in Catalytic Asymmetric Synthesis, 2nd ed. (Ed.: I. Ojima), Wiley/VCH, 2000, 399–428.

     
  • Asymmetric, Catalytic Phenyl Transfer to Aldehydes: Enantioselective Synthesis of Diarylmethanols
    C. Bolm, N. Hermanns, J. P. Hildebrand, K. Muñiz, Angew. Chem. 2000, 112, 36073609; Angew. Chem. Int. Ed. 2000, 39, 3465–3467.

     
  • α-Trialkylsilylsubstituierte α-Aminosäuren
    C. Bolm, A. Kasyan, K. Drauz, K. Günther, G. Raabe Angew. Chem. 2000, 112, 2374–2376; Angew. Chem. Int. Ed. 2000, 39, 2288–2290.

     
  • Configurational Control in Stereochemically Pure Ligands and Metal Complexes for Asymmetric Catalysis
    C. Bolm, K. Muñiz, Chem. Eur. J. 2000, 6, 2309–2316.

     
  • Catalytic Coupling of Aryl Sulfonates with sp2-Hybridized Nitrogen Nucleophiles: Palladium- and Nickel-catalyzed Synthesis of N-Aryl Sulfoximines
    C. Bolm, J. P. Hildebrand, J. Rudolph, Synthesis 2000, 911–913.

     
  • Zirconium-Mediated Asymmetric Baeyer–Villiger Oxidation
    C. Bolm, O. Beckmann, Chirality 2000, 12, 523–525.

     
  • Regio- and Stereoselective Ring-Opening Reactions of Chiral Substituted Spiro[2.4]hepta-4,6-dienes: A New, Simple, and Versatile Approach to the Synthesis of Optically Active Bidentate Cyclopentadienyl-Phosphine Ligands. X-Ray Crystal Structure of (S)-[Rh(η2-C2H4) (η5-C5H4CH2CHPhPPh2-кP)]
    S. Circuelos, U. Englert, A. Salzer, C. Bolm, A. Maischak, Organometallics 2000, 19, 2240–2242.

     
  • Asymmetric Epoxidation of Allylic Alcohols Using Vanadium Complexes of (N)-Hydroxy-[2.2]paracylophane-4-carboxylic Amides
    C. Bolm, T. Kühn, Synlett 2000, 899–901.

     
  • Diastereoselective Synthesis of Ferrocenyl Sulfoximines with Planar and Central Chirality
    C. Bolm, M. Kesselgruber, K. Muñiz, G. Raabe, Organometallics 2000, 19, 1648–1651.

     
  • Preparation and Catalytic Enantioselective Reactions of Chiral C 3-Symmetric Tris(Oxazoline)s Derived from Kemp's Triacid
    T.-H. Chuang, J.-M. Fang, C. Bolm, Synth. Commun. 2000, 30, 1627–1641.

     
  • Catalytic Synthesis of Aldehydes and Ketones under Mild Conditions Using TEMPO/Oxone®
    C. Bolm, A. S. Magnus, J. P. Hildebrand, Org. Lett. 2000, 2, 1173–1175.

     
  • Palladium-Catalyzed N-Arylation of Sulfoximines with Aryl Bromides and Aryl Iodides
    C. Bolm, J. P. Hildebrand, J. Org. Chem. 2000, 65, 169–175.